Synthesis gas or "Syngas" is being recognized as a viable energy source worldwide, particularly for stationary power generation due to its wide availability as a product of bio and fossil fuel gasification. There are, however, gaps in the fundamental understanding of syngas combustion and emissions characteristics, especially at elevated pressures that are relevant to practical combustors. This paper presents a numerical and experimental investigation of the combustion and NO, characteristics of syngas fuel with varying composition, pressure and strain rate. Experiments were performed at atmospheric conditions, while the simulations considered different pressures. Both experiments and simulations indicate that stable non-premixed and partially premixed counterflow flames (PPFs) can be established for a wide range of syngas compositions and strain rates. Three chemical kinetic models, GRI 3.0, Davis et A., and Mueller et al. are examined. The Davis et al. mechanism is found to agree best with the experimental data, and hence used to simulate the PPF structure at different pressure and fuel composition. For the pressure range investigated, results indicate a typical double flame structure with a rich premixed reaction zone (RPZ) on the fuel side and a non-premixed reaction zone (NPZ) on the oxidizer side, with RPZ characterized by H-2 oxidation, and NPZ by both H2 and CO oxidation. While thermal NO is found to be the dominant route for NO production, a reburn route, which consumes NO through NO + O + M -> NO2 + M and H + NO + M -> HNO + M reactions, becomes increasingly important at high pressures. The amount of NO formed in syngas PPFs first increases rapidly with pressure, but then levels off at higher pressures. At a given pressure, the peak NO mole fraction exhibits a non-monotonic variation with syngas composition, first decreasing to a minimum value, and then increasing as the amount of CO in syngas is increased. This implies the existence of an optimum syngas composition that yields the lowest amount of NO production in syngas PPFs, and can be attributed to the combined effects of thermal and reburn mechanisms. (C) 2007 Elsevier Ltd. All rights reserved.