Chemical-looping combustion (CLC) has emerged as a promising option for CO(2) capture because this gas is inherently separated from the other flue gas components and thus no energy is expended for the separation. This technology would have some advantages if it could be adapted for its use with coal as fuel. in this sense, a process integrated by coal gasification and CLC could be used in power plants with low energy penalty for CO(2) capture. This work presents the results obtained in the combustion of syngas as fuel with a Ni-based oxygen carrier prepared by impregnation in a CLC plant under continuous operation. The effect on the oxygen carrier behaviour and the combustion efficiency of several operating conditions was determined in the continuous CLC plant. High combustion efficiencies (similar to 99%), close to the values limited by thermodynamics, were reached at oxygen carrier-to-fuel ratios higher than 5. The temperature in the FIR had a significant influence, although high efficiencies were obtained even at 1073 K. The syngas composition had small effect on the combustion, obtaining high and similar efficiencies with syngas fuels of different composition, even in the presence of high CO concentrations. The low reactivity of the oxygen carrier with CO seemed to indicate that the water gas shift reaction acts as an intermediate step in the global reaction of the syngas in a continuous CLC plant. Neither agglomeration nor carbon deposition problems were detected during 50 h of continuous operation in the prototype. The obtained results showed that the impregnated Ni-based oxygen carrier could be used in a CLC plant for the combustion of syngas produced in an integrated gasification combined cycle (IGCC). (C) 2008 Elsevier Ltd. All rights reserved.