Journal of Adhesion, Vol.68, No.3, 203-228, 1999
Relationship between viscoelastic and peeling properties of model adhesives. Part 2. The interfacial fracture domains
The viscoelastic and peeling properties of polybutadiene/tackifying resin compatible blends have been studied in detail. Viscoelastic properties have been described through the variations of the complex shear modulus, G*(omega), as a function of frequency, omega, and peeling properties through the variations of peeling force (F) as a function of peeling rate (V). The first paper of this series presented the cohesive fracture domain and the present paper explores the interfacial fracture domain: (i) rubbery interfacial (interfacial i).; (ii) stick-slip; (iii) glassy interfacial (interfacial 2). After a general survey of the properties in the three domains we present a quantitative relationship between the peeling anti linear viscoelastic properties as a function of the adhesive formulation, discussing the use of time-temperature equivalence for adhesive properties. The third part of the paper presents the trumpet model of de Gennes describing the crack shape and propagation: starting from a mechanical analysis of the peeling test, it is shown how one may calculate the variations of the peeling force as a function of peeling rate in the various interfacial fracture domains: this model defines a single interfacial fracture criterion which coexists with the cohesive fracture criterion defined earlier, whatever the fracture location. We present as a conclusion a critical discussion of the relevance and physical meaning of such a criterion and present a new outlook for the modeling and improvement of adhesive formulations.
Keywords:POLYMER MELTS