화학공학소재연구정보센터
학회 한국고분자학회
학술대회 2018년 가을 (10/10 ~ 10/12, 경주컨벤션센터)
권호 43권 2호
발표분야 분자전자 부문위원회 II
제목 Soft-templated tellurium-doped mesoporous carbons as a Pt-free electrocatalyst for high-performance dye-sensitized solar cells
초록 Among the photovoltaic devices, dye-sensitized solar cell (DSSC) is one of the promising energy conversion devices because of its low fabrication cost, environmental friendly nature and high conversion efficiency. However, the use of rare metals such as Pt as a counter electrode (CE) is one of a drawback of DSSC devices for real-life applications. Therefore, in this study, soft-templated tellurium-doped mesoporous carbons (Te-SMC) were synthesized by the simple pyrolysis of PAN-b-PBA block copolymer in the presence of tellurium precursor for replacing the Pt CE. In the results of catalytic performances, Te-SMC exhibited outstanding electrocatalytic activity for cobalt and iodine redox couples. The results show that a maximum conversion efficiency of 11.64 and 9.67 % can be achieved under one sun illumination (AM 1.5G) for SGT021/Co(bpy)32+/3+ and N719/I-/I3-based devices, respectively.
저자 김창기, 김환규
소속 고려대
키워드 dye-sensitized solar cells; counter electrode; soft-templated tellurium-doped mesoporous carbons; PAB-b-PBA block copolymer
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