| 학회 |
한국고분자학회 |
| 학술대회 |
2021년 가을 (10/20 ~ 10/22, 경주컨벤션센터) |
| 권호 |
46권 2호 |
| 발표분야 |
대학원생 구두발표(토론I): 분자전자용 공액고분자 소재 및 소자의 미래 |
| 제목 |
Exploring Wholly Doped Conjugated Polymers for Optimization of Electrical Conductivity and Related Thermoelectric Properties |
| 초록 |
Molecular doping is a common strategy to improve the electrical conductivity of Conjugated Polymers(CPs). Herein, we suggest a novel doping method, ‘hybrid doping‘, that can fully extract maximum of employed CPs by wholly doping crstalline and amorphous regions. We strategically hybridized mixture blending and sequential processes and made use of each process’s advantages. Using the hybrid doping, we achieved of P3HT up to 80.39 S cm-1 Furthermore, hybrid doping effectively worked for less crystalline CP, PIDF-BT, by increasing its up to 639.04 S/cm which indicates the general applicability of hybrid doping. Remarkably conductive CP films prepared by hybrid doping complemented decreased Seebeck coefficient and featured optimized thermoelectric effect, power factor up to 76.05 µWm-1K-2. Based on these results, we believe that this simple but very effective hybrid doping method can be a versatile process for optimizing both electrical and thermoelectrical properties of various CPs. |
| 저자 |
윤상은1, 강영권2, 전경국3, 전도현4, 이상연5, 고서진6, 김태경4, 서형탁1, 김봉기2, 김종현1
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| 소속 |
1아주대, 2건국대, 3전자기술(연), 4한국외국어대, 5KAIST, 6한국화학(연) |
| 키워드 |
conjugated polymers; doping; sequential doping; blend doping; electrical conductivity; theroelectric effect; hybrid doping
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| E-Mail |
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