| 학회 |
한국고분자학회 |
| 학술대회 |
2009년 봄 (04/09 ~ 04/10, 대전컨벤션센터) |
| 권호 |
34권 1호 |
| 발표분야 |
기능성 고분자 |
| 제목 |
Size control of porphyrin H-aggregates for photovoltaic applications |
| 초록 |
Size control of porphyrin H-aggregates is of interest due to its potential applications for the molecular electronic devices such as a single electron transistors. Size-controlled molecular wires can build a bridge over the macroscale gap between anode and cathode. Porphyrin molecule with 22 π-electrons enables strong interaction which can facilitate the formation of one-dimensional H-aggregates via face-to-face stacking. We report on the size control of porphyrin H-aggregates consisting of a number of alkyl-appended zinc porphyrins. Using UV-Vis spectroscopy and Dynamic Light Sc! attering(DLS), we have revealed that the size of porphyrin H-aggregates was decreased with the concentration of 1,4-diazabicyclo[2.2.2]octane(DABCO) that have strong interactions with zinc metal of porphyrin. |
| 저자 |
노경진, 고유선, 최명석
|
| 소속 |
건국대 |
| 키워드 |
porphyrin; H-aggregation; DABCO; size control
|
| E-Mail |
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