| 학회 |
한국고분자학회 |
| 학술대회 |
2004년 봄 (04/09 ~ 04/10, 고려대학교) |
| 권호 |
29권 1호, p.250 |
| 발표분야 |
고분자 합성 |
| 제목 |
High-throughput synthesis of new catalysts and polymerization of norbornene utilizing the parallel polymerization reactor system |
| 초록 |
The vinyl-type polynorbornene, the one of three type of polymerization, is of interest as a specialty polymer because of its good mechanical strength, heat resistivity, and optical transparency for applications such as deep ultraviolet photoresists and interlevel dielectrics in microelectronic applications; it is also of interest as a cover layer for liquid-crystal displays. Herein, Herein, we report the development of new Ni(II), Pd(II), and Co(II) catalysts containing ligands of pyrazolylpyridine derivatives by combinatorial and high-throughput synthesis technology. The catalysts generated by combination of new pyrazolylpyridine ligands with various transition metal in an automated parallel synthesizer, served as Ni(II), Pd(II), and Co(II) catalysts for norbornene polymerization. Vinyl-type polynorbornene was polymerized utilizing the self-made parallel polymerization reactor system. |
| 저자 |
조현용1, 홍대식1, Liqiang Cui1, 공영대2, 우성일1
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| 소속 |
1한국과학기술원 생명화학공학과 /초미세화학공정시스템연구센터(CUPS), 2한국화학(연) |
| 키워드 |
norbornene; parallel polymerization reactor system; High-throughput synthesis; catalysts
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| E-Mail |
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