| 학회 |
한국화학공학회 |
| 학술대회 |
2005년 봄 (04/22 ~ 04/23, 여수대학교) |
| 권호 |
11권 1호, p.18 |
| 발표분야 |
고분자 |
| 제목 |
Methly Acrylate Polymerization using New Zr(IV), Fe(II), Co(II) Catalysts Bearing N,N,N-Chelate Ligand |
| 초록 |
The homopolymerization of methly Acrylate (MA) was investigated with Zirconium(IV), Iron(II), Cobalt(II) complexes bearing 2,6-bis(2-benimidazyl)pyridine (bbipy) and with methylaluminoxane (MAO) as an activator. bbipy is tridentate ligand as tree nitrogen coordinate to metal center. In bulk polymerization of MA with bbipy metal complex with MAO, polymethacrylate (PMA) was formed successfully. When we tried bulk polymerization of MA with MAO not including any metal catalysts, we got little amount of PMA. However, this PMA had different properties from PMA that was polymerized with metal catalyst and MAO. |
| 저자 |
조현용1, 홍대식1, Liqiang Cui1, Naresh Hiralal Tarte1, 공영대2, 우성일1
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| 소속 |
1한국과학기술원 / 초미세화학공정시스템 연구센터(CUPS), 2한국화학(연) |
| 키워드 |
Polymerization; Methly Acrylate; MAO
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| E-Mail |
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| 원문파일 |
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