| 초록 |
Exposure to toxic chemical warfare agents and related toxins is a potential hazard to the armed forces and to civilian populations, since CW agents are stockpiled by several nations and, other nations and groups actively seek to acquire these materials. Bis-(2-chloroethyl)sulfide (HD or mustard gas) is one of the toxic blister agents which was occasionally used by some nation or groups. We conducted a series of decontamination experiments for HD on various nano-particles including UiO-66-X(X=Cl, F, NO2, NH2, OH, etc) series Metal-Organic-Frameworks in aqueous alcoholic solution at room temperature. During the decontamination process, remaining HD and decomposition products of HD were analyzed by GC/FID and GC/MS for determining the reaction rates and routes of HD decomposition. Some functional groups accelerate the decomposition rate of HD compare to the pristine UiO-66 in aqueous alcoholic solution, but some cases negatively affects. |
