화학공학소재연구정보센터
학회 한국공업화학회
학술대회 2022년 봄 (05/11 ~ 05/13, 제주국제컨벤션센터(ICC JEJU))
권호 26권 1호
발표분야 포스터-환경·에너지
제목 A nover porous material MOFs-derived carbons (MDCs) impregnated Cu(I)Zn for high CO adsorption capacity, and and CO/CO2 selectivity
초록  Selective adsorption research on carbon monoxide (CO) that can be used as an industrial raw material for C1 Chemicals is an important task facing carbon neutralization. In this study, MOFs-derived carbons (MDCs) derived from MOFs are introduced as novel adsorption with high thermal and moisture stability and can be selectively designed pore size. Also, the unique porous structure of MOFs can be utilized as it is. Although original MDCs have a higher adsorption capacity for CO2 than CO, it shows a high adsorption CO property according to the loading concentration of CU(I) and Zn. The ideal absorbed solution theory (IAST) are utilized to predict the CO/CO2​ selectivity with the CO and CO2​ adsorption capacity in the isothermal state. Cu(I)ZN@MDCs show improved CO adsorption capacity with high CO/CO2​ selectivity, and can be regarded as an effective material as an adsorbent material for effective CO/CO2 separation.​​​​
저자 김성천1, 정다솜2, 최시영3, 박제성4
소속 1한국과학기술원(KAIST) / 한국생산기술(연), 2인하대, 3한국과학기술원(KAIST), 4한국생산기술(연)
키워드 MOFs; MDC; CO adsorption; porous material
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