화학공학소재연구정보센터
학회 한국화학공학회
학술대회 2006년 봄 (04/20 ~ 04/21, 대구 인터불고 호텔)
권호 12권 1호, p.1068
발표분야 촉매 및 반응공학
제목 Pt-based Catalysts for the Preferential CO Oxidation
초록 Pt-Ni/γ-Al2O3 and Pt-Co/Y-ZrO2 were selected as promising catalysts for the preferential CO oxidation to remove a residual CO in hydrogen stream not to deactivate anode of polymer electrolyte membrane fuel cell (PEMFC). Effects of preparation and reaction variables on CO conversion were examined over both catalysts. CO chemisorption, temperature programmed reduction (TPR), and transmission electron microscopy (TEM) were conducted to find out the cause of enhanced catalytic activity. The bimetallic phase of Pt-Ni and Pt-Co appeared to be essential for selective CO oxidation especially at low temperatures.
저자 고은용1, 박은덕1, 서경원1, 이현철2, 김순호2, 이두환2
소속 1아주대, 2삼성종합기술원
키워드 Pt; Ni; Co; PROX; Fuel Cell
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