| 학회 |
한국고분자학회 |
| 학술대회 |
2018년 가을 (10/10 ~ 10/12, 경주컨벤션센터) |
| 권호 |
43권 2호 |
| 발표분야 |
대학원생 구두발표(영어발표, 발표15분) |
| 제목 |
Self-Assembled Morphologies of Polystyrene-b-Poly(1,4-butadiene) Confined in Cone-Shaped Templates: Effect of Confinement Geometries |
| 초록 |
we demonstrated the self-assembled morphologies of polystyrene-b-poly(1,4-butadiene) (PS-b-PB) confined in conical templates. Based on experimental observation, we concluded that three thermodynamic factors work competitively in the conical confinement system; the interfacial energy of air- polymer, the entropic penalty at the vertices, and the surface energy of the AAO wall. To systematically examine the effect of three competing factors, two additional templates with different bottom geometries (truncated conical and cylindrical templates) were fabricated to control the vertex curvature of conical pores. In an attempt to identify the experimental observation more thoroughly, simulated annealing studies of diblock copolymers along with 3D imaging by TEM tomography were also performed. |
| 저자 |
김영걸1, Takeshi Higuchi2, 황성열1, An-Chang Shi3, Baohui Li4, Hiroshi Jinnai2, 차국헌1
|
| 소속 |
1서울대, 2Tohoku Univ., 3Mcmaster Univ., 4Nankai Univ. |
| 키워드 |
Self-Assembled Morphology; Nanoconfinement; Conical Pores; Simulated Annealing; TEM Tomography
|
| E-Mail |
|
