| 학회 | 한국공업화학회 |
| 학술대회 | 2018년 가을 (10/31 ~ 11/02, 제주국제컨벤션센터(ICC JEJU)) |
| 권호 | 22권 2호 |
| 발표분야 | (여성인재육성위원회) 젠더혁신 전문가 특강 및 WISET-KISEC 젊은연구자상 수상자발표 |
| 제목 | Functional Group Controls in Metal-Organic Frameworks for CO2 Fixation |
| 초록 | The coupling reaction between CO2 and epoxides to organic cyclic carbonates is one of the powerful ways to fix CO2 for useful chemicals. Recently, various organometallic catalysts (e.g., aluminum, zinc, titanium, etc.) have been developed for the efficient CO2 cycloaddition and metal-organic frameworks (MOFs) have been reported as efficient catalysts for this reaction. The catalytic activity of MOFs on CO2 cycloaddition varies depending on the metal clusters and ligands. We have synthesized Zr-MOFs with various functional groups (e.g., -OH, -NH2, -X, and –NO2) and utilized it to the CO2 cycloaddition reaction as catalysts. As a result, it was confirmed that the hydroxy functional group works most effectively under high temperature. Additionally, we have expanded our findings to various combinations of metal and ligand to find out the best MOF catalyst for CO2 fixation. |
| 저자 | 노진미, 박명환, 김영조, 김민 |
| 소속 | 충북대 |
| 키워드 | Metal-organic frameworks(MOFs); Catalyst; CO2 cycloaddition; Functional group |
