화학공학소재연구정보센터
학회 한국고분자학회
학술대회 2019년 가을 (10/09 ~ 10/11, 제주컨벤션센터)
권호 44권 2호
발표분야 기능성 고분자
제목 Synthesis and properties of azobenzene containg polymer for blue updatable hologram
초록 When the azobenzene group absorbs the light, cis-trans photoisomerization occurs. As a result of photoisomerization, azobenzene containg polymer have a refractive index change after photo-irradiation. Using such reversible refractive index change characteristics, the azovenzene polymers were studied as one of rewritable hologram materials. In this study, we designed a molecular structure that maximizes the refractive index modulation by photoisomerization under the blue laser wavelength (~ 460 nm), and azobenzene containg PMMA based polymer was synthesized. The molecular structure and physical properties of the polymer used as the blue hologram rewritable material were characterized by NMR, UV-vis, DSC and GPC, and the hologram recording characteristics such as diffraction efficiency and refractive index change after photo-irradiation were also studied.
저자 강이영1, 강혜주1, 주경일2, 김학린2, 가재원1
소속 1한국화학(연), 2경북대
키워드 Hologram; azobenzene; PMMA
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