| 학회 | 한국고분자학회 |
| 학술대회 | 2005년 봄 (04/14 ~ 04/15, 전경련회관) |
| 권호 | 30권 1호, p.532 |
| 발표분야 | 고분자 구조 및 물성 |
| 제목 | The Effect of Chain Architecture of In-Situ Formed Copolymers on Interfacial Morphology of Reactive Polymer Blends |
| 초록 | The effect of chain architecture of in-situ formed copolymers on interfacial morphology of reactive polymer blends was investigated by atomic force microscopy and transmission electron microscopy. Monofunctional glycidyl methacrylate-terminated polystyrene (PS-GMA) and poly(methyl methacrylate) with carboxylic acid functional groups (PMMA-COOH), which were both synthesized anionically, were sequentially spin-coated on silicone wafer and reacted at 180 oC for various times. To allow different molecular architechures of in-situ formed copolymers, three different kinds of PMMA-COOH were synthesized, where the positions of carboxylic acid functional groups were located at a third, the middle, and the end of the PMMA chain. We found that the chain architectures of copolymers formed in-situ at the interface significantly affected the reaction rate and interface roughness. Although the reaction rate for the formation of the Y-shaped graft copolymer from the mid-functionalized PMMA-COOH is slower than that of diblock copolymer from the end-functionalized PMMA-COOH, the interface area generated by the former was larger than that generated by the latter. |
| 저자 | 김황용, 고동한, 류두열, 정운용, 김진곤 |
| 소속 | 포항공과대 |
| 키워드 | reactive blende |
