| 학회 |
한국공업화학회 |
| 학술대회 |
2012년 봄 (05/09 ~ 05/11, 김대중컨벤션센터) |
| 권호 |
16권 1호 |
| 발표분야 |
지경부 성과발표 |
| 제목 |
Nitration of halopropane to nitropropane over several catalysts |
| 초록 |
This study realize the industrial nitration process of 2-halopropane under a room temperature and pressure using a modified solid catalysts in a miniature reactor. The conversion yield increased by 10% and this maintained several month in a continuous reaction, while the conversion yield dropped down at the no catalytic reaction. We have previously reported that ZrO2, ZrO2, NaOH-ZrO2 and NaOH- ZrO2 could act as a catalyst for the nitration of 2-halopropane. This solide base catalysts was treated with 10% aqueous sulfuric acid, then dried at 120℃ and calcined at 600℃ in air. 2-halopropane was used NaNO2 and Urea. This solution was stirring for 5 hours at room temperature. |
| 저자 |
장태선1, 고상길1, 김진억2, 노기윤2, 신채호3
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| 소속 |
1한국화학(연), 2금호석유화학, 3충북대 |
| 키워드 |
Nitration; halopropane; nitropropane
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| E-Mail |
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