화학공학소재연구정보센터
학회 한국재료학회
학술대회 2021년 봄 (05/12 ~ 05/14, 광주 김대중컨벤션센터)
권호 27권 1호
발표분야 G. 나노/박막 재료 분과
제목 전기도금 공정에 의하여 제조된 Co-P 합금 박막의 자성 특성에 대한 연구
초록 Nanocrystalline cobalt-phosphorus (Co100-xPx) thin films were electrodeposited and their extrinsic magnetic properties were systematically studied by controlling various synthesis parameters. The crystalline thin films exhibited the perpendicular anisotropy which had the behavior of strip domains. The incorporation of phosphorus (P) atoms into cobalt (Co) lattice structure resulted in the transition from single to pseudo-domain particles. As P content augmented in the crystalline deposits, P precipitation at the grain boundary served as pinning sites, resulting in higher coercivity. Further increase in P content reduced the crystallinity of the deposits and thereby lowered perpendicular anisotropy and coercivity. Promotion of P content was observed at higher NaH2PO2 concentration, lower pH, and smaller film thickness. Temperature was also adjusted to tune P content by controlling the fraction of free Co2+ ions and complexes Co(NH3)6 in solution.
저자 Dung T. To1, 박덕용2, Nosang V. Myung3, 유봉영4, Saba Seyedmahmoudbaraghani2, 박선화5
소속 1Univ. of Norte Dame, 2Department of Chemical and Biomolecular Engineering, 3한밭대, 4Univ. of Notre Dame, 5한양대
키워드 Electrodeposition; Co-P thin film; Nanocrystalline; Magnetic property
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