화학공학소재연구정보센터
학회 한국공업화학회
학술대회 2013년 봄 (05/01 ~ 05/03, ICC JEJU)
권호 17권 1호
발표분야 포스터-촉매
제목 Selective Hydrogenation of Allylic Alcohols to Saturated Alcohols by Efficient Heterogeneous Ruthenium Catalyst
초록 The easily prepared solid-supported ruthenium could act as a heterogeneous catalyst for selective transfer hydrogenation of allylic alcohols via an efficient sequential process of isomerization and Meerwein-Ponndorf-Verley-type (MPV-type) reduction. The various substrates including terminal, internal, and cyclic allylic alcohols were converted to the desired products in high yield with 2-propanol as both proton source and solvent. The catalyst could be reused with retention of the high catalytic performance.
저자 김정원, 서은경
소속 강원대
키워드 Heterogeneous catalyst; Hydrogenation; Isomerization; MPV-type reduction
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