학회 |
한국공업화학회 |
학술대회 |
2013년 봄 (05/01 ~ 05/03, ICC JEJU) |
권호 |
17권 1호 |
발표분야 |
포스터-촉매 |
제목 |
Selective Hydrogenation of Allylic Alcohols to Saturated Alcohols by Efficient Heterogeneous Ruthenium Catalyst |
초록 |
The easily prepared solid-supported ruthenium could act as a heterogeneous catalyst for selective transfer hydrogenation of allylic alcohols via an efficient sequential process of isomerization and Meerwein-Ponndorf-Verley-type (MPV-type) reduction. The various substrates including terminal, internal, and cyclic allylic alcohols were converted to the desired products in high yield with 2-propanol as both proton source and solvent. The catalyst could be reused with retention of the high catalytic performance. |
저자 |
김정원, 서은경
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소속 |
강원대 |
키워드 |
Heterogeneous catalyst; Hydrogenation; Isomerization; MPV-type reduction
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E-Mail |
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