학회 |
한국화학공학회 |
학술대회 |
2019년 가을 (10/23 ~ 10/25, 대전컨벤션센터) |
권호 |
25권 2호, p.1948 |
발표분야 |
재료 (Materials) |
제목 |
Synthesis RhAg bimetallic composite nanoparticles for improved catalysts on direct synthesis of hydrogen peroxide generation |
초록 |
This study reports on the aqueous-phase synthesis of rhodium-silver (RhAg) bimetallic composite nanoparticles with a controllable Rh/Ag ratio. Due to the high cost of Rh compared with Ag, the RhAg nanoparticles were synthesized in two steps: the synthesis of Ag nanoparticles and the formation of a Rh-rich RhAg area on the surface of the Ag nanoparticles. Transmission electron microscopy and corresponding elemental mapping analyses exhibited that the synthesized 20 nm-sized quasi-spherical RhAg nanoparticles were composed of Ag-rich and Rh-rich area, respectively. Considering the amount of Rh used and productivity, the RhAg nanoparticles with a Rh content of 0.8% exhibited the best catalytic performance for the direct H2O2 generation reaction. |
저자 |
장양필, 남효빈, 송요셉, 이승용, 안재평, 유태경
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소속 |
경희대 |
키워드 |
재료 |
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