화학공학소재연구정보센터
학회 한국공업화학회
학술대회 2020년 가을 (10/28 ~ 10/30, 광주 김대중컨벤션센터(Kimdaejung Convention Center))
권호 24권 1호
발표분야 포스터-촉매
제목 Use of Stoichiometry as a Major Synthetic Variable to Improve Properties of Vanadate Surfaces in Catalyzing Low-Temperature NOX Reduction
초록 Vanadate is a particular class of intriguing, emerging catalytic phase proper to reduce NOX with NH3 at low temperatures (SCR). The vanadates are given a spectrum of binary phase diagrams constituting of metal (M) oxides and V2O5, by which the coordination numbers or geometries of M/V can be readily modulated upon the change in the stoichiometries defined in a specific vanadate (e.g., CuXV2OX+5, where X=1, 2, 3, and 5). In this presentation, we showcase our study on ‘how catalytic property of the vanadate can be tuned by altering its stoichiometry and bring about distinct SCR consequence at low temperatures’. A host of characterization techniques served to clarify the dissimilar traits of the vanadate surfaces, which were related to their SCR performance in terms of NOX conversion, N2 selectivity, longevity, etc.
저자 안효진, 권동욱, Ha Heon Phil, 김종식
소속 한국과학기술(연)
키워드 vanadate; stoichiometry; coordination; SCR
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