| 학회 |
한국화학공학회 |
| 학술대회 |
2021년 가을 (10/27 ~ 10/29, 광주 김대중컨벤션센터) |
| 권호 |
27권 2호, p.1462 |
| 발표분야 |
공업화학 |
| 제목 |
Ferricyanide-intercalated flavoenzyme-modified pseudocapacitive electrode |
| 초록 |
Basically, an enzyme belonging to the proteins which is one of biomacromolecules is electrically non-conductive, and can be used as an insulating material for capcitors. In this work, we fabricate a ferricyanide-intercalated flavoenzyme-based pseudocapacitor which acts as an electric double-layer capacitor and simultaneously as the pseudocapacitor. Cyclovoltametric intercalation of flavoenzymes with ferricyanide activates pseudocapacitive property of the enzyme-modified pseudocapacitive electrode. Indium tin oxide was employed as the substrate to immobilize methyl tryptophan oxidase (MTO) via amino-glutaraldehyde cross-linking chemistry. The ferricyanide-intercalated MTO-based pseudocapacitor is characterized by the cyclic voltammetry, electrochemical impedance spectroscopy, atomic force microscopy, and Fourier-transformed infrared spectroscopy. Charging and discharging characteristics and long-term stability of the pseudocapacitor are also presented. |
| 저자 |
진준형, 김윤경, 박준희, 성수환, 이강열, 양인환
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| 소속 |
경기대 |
| 키워드 |
전기화학 |
| E-Mail |
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| 원문파일 |
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