| 학회 |
한국고분자학회 |
| 학술대회 |
2017년 봄 (04/05 ~ 04/07, 대전컨벤션센터) |
| 권호 |
42권 1호 |
| 발표분야 |
대학원생 구두발표 (발표15분) |
| 제목 |
One-step, Vapor Phase Synthesis of Crosslinked Ionic Polymer Thin Films for Oil/Water Separation Membrane |
| 초록 |
Ionic polymers have been applied to various research field due to their unique properties. However, the ionic polymers could not have been synthesized in vapor phase because of the nonvolatile monomers. Here, we suggest a new synthetic method for crosslinked ionic polymers (CIPs) in vapor phase via initiated chemical vapor deposition (iCVD). 2-(Dimethylamino)ethyl methacrylate (DMAEMA) and 4-vinylbenzyl chloride (VBC) are introduced into the iCVD reactor in vapor phase. Copolymerization is occurred on the surface of the substrate, and simultaneously, Menshutkin reaction proceeds between tertiary amine in DMAEMA and benzylic chloride in VBC. Highly crosslinked p(DMAEMA-co-VBC) film is formed with ionic ammonium-chloride complex. The CIP thin film is applied to the surface modification of the oil/water separation membrane. With the hydrophilic and underwater-oleophobic CIP-coated membrane, excellent separation efficiency (99%) and outstanding flux (avg. 2.32×105 Lm-2h-1) are achieved. |
| 저자 |
신지혜1, 주문규1, 김지연2, 유재범1, 유영민3, 곽무진1, 오명석1, 임성갑1
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| 소속 |
1KAIST, 2LG화학, 3삼성전자 |
| 키워드 |
crosslinked ionic polymer; initiated chemical vapor deposition (iCVD); Menshutkin reaction in vapor phase; oil/water separation membrane
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| E-Mail |
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