| 학회 |
한국고분자학회 |
| 학술대회 |
2021년 가을 (10/20 ~ 10/22, 경주컨벤션센터) |
| 권호 |
46권 2호 |
| 발표분야 |
고분자합성 |
| 제목 |
Synthesis of Functional Polypropylene via Postpolymerization Deoxygenation |
| 초록 |
Functional polyolefins are high-value-added polymeric materials with improved materials properties by introducing polar functional groups into the nonpolar polyolefinic backbone. Synthesis of functional polypropylene is particularly challenging because the monomer is not suited for radical polymerization. Here we discuss a postpolymerization modification route to functional polypropylene by borane-catalyzed deoxygenation of polyacrylate precursors. Reactivity of acrylate model compounds with different pendant groups will be investigated to understand substrate-dependent reaction pathways to the propylene group. The results will be extended to the polymer reactions to produce functional polypropylenes with controlled functional group density. |
| 저자 |
오태석, 전성장, 김영호, 서명은
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| 소속 |
한국과학기술원 |
| 키워드 |
Chemoselectivity; Deoxygenation; Functional Polypropylene
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| E-Mail |
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