화학공학소재연구정보센터
학회 한국고분자학회
학술대회 2014년 봄 (04/10 ~ 04/11, 대전 컨벤션센터)
권호 39권 1호
발표분야 고분자합성
제목 One-step synthesis of poly(oxazoline)-based amphiphilic block copolymers using a dual initiator for RAFT polymerization and CROP
초록 The increasing interest in amphiphilic block copolymers arises mainly from their self-organization in water. Poly(oxazoline)-based amphiphilic block copolymers can find applications in macromolecular emulsifiers and dispersants. This study reports a facile one-step synthesis of poly(2-methyl-2-oxazoline)- and poly(2-ethyl-2-oxazoline)-based amphiphilic diblock copolymers using 4-cyano-4-(dodecylthiocarbonothioylthio)pentyl-4-methylbenzenesulfonate as a dual initiator for reversible addition fragmentation chain transfer (RAFT) polymerization and cationic ring-opening polymerization (CROP).
저자 유영창, 서자덕, 육지호
소속 인하대
키워드 ROP; RAFT; dual initiator; one-step
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