| 학회 |
한국고분자학회 |
| 학술대회 |
2013년 가을 (10/11 ~ 10/12, 창원컨벤션센터) |
| 권호 |
38권 2호 |
| 발표분야 |
고분자합성 |
| 제목 |
One-pot synthesis of poly(ε-caprolactone)-b-poly(vinyl alcohol) block copolymers using a dual initiator for RAFT polymerization and ROP |
| 초록 |
An efficient one-pot procedure for the synthesis of amphiphilic poly(ε-caprolactone)-b-poly(vinyl alcohol) (PCL-b-PVA) block copolymers using a hydroxyl-functionalized RAFT agent, 2-hydroxyethyl 2-(ethoxycarbonothioylthio) propanoate, as a dual initiator for RAFT polymerization and ROP was successfully developed. The PCL block was first polymerized by the ROP of ε-caprolactone (CL) using diphenyl phosphate as a catalyst, followed by the RAFT polymerization of vinyl chloroacetate (VClAc) after quenching the ROP of CL with 4-dimethyamino pyridine. The resulting PCL-b-PVClAc block copolymers were directly aminolyzed to PCL-b-PVA block copolymers in the same pot. The resulting PCL-b-PVA block copolymers showed very narrow molecular weight distributions. |
| 저자 |
유영창, 신상진, 고광덕, 육지호
|
| 소속 |
인하대 |
| 키워드 |
dual initiator; RAFT; ROP; PVA; PCL
|
| E-Mail |
|
