| 학회 |
한국고분자학회 |
| 학술대회 |
2012년 봄 (04/12 ~ 04/13, 대전컨벤션센터) |
| 권호 |
37권 1호 |
| 발표분야 |
기능성 고분자 |
| 제목 |
A synthetic approach to a fullerene-rich dendron and its linear polymer and performance of the solar cells |
| 초록 |
Through the esterification of an acyl chloride functionalized fullerene precursor with dendritic alcohol, a fullerene-rich dendron containing a norbornene unit at the focal point is prepared for ring-opening metathesis polymerization to obtain its linear polymer with a unimodal and narrow molar mass distribution (PDI = 1.08) by a progressive addition of catalysts. Moreover the potential applications of these dendritic-type fullerenes in organic photovoltaic devices(OPVs), the active layers in bulk heterojunction OPVs were fabricated with P3HT. The weight ratio of P3HT to fullerene-rich dendron was 1 : 1, whereas in the case of fullerenerich linear polymer the ratio was 1 : 0.5. The photovoltaic performance based on fullerenerich dendron shows a Jsc of 5.23 mA cm-2, a Voc of 0.50 V, a fill factor (FF) of 0.52 and PCE of 1.36%. The device using fullerene-rich linear polymer delivers performance with a Jsc of 3.61 mA cm-2, a Voc of 0.44 V, a FF of 0.33, decreasing the PCE to 0.52%. |
| 저자 |
윤명희1, 김종기1, 이정훈1, Fred Wudl2, 양창덕3, 김진영1
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| 소속 |
1울산과학기술대, 2Univ. of California, 3Santa Barbara |
| 키워드 |
유기태양전지; fullerene
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| E-Mail |
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