화학공학소재연구정보센터
학회 한국고분자학회
학술대회 2021년 가을 (10/20 ~ 10/22, 경주컨벤션센터)
권호 46권 2호
발표분야 분자전자 부문위원회 Ⅰ,Ⅱ
제목 Efficient Blue Phosphorescent Ir-Complexes with Terphenyl Modified 2-Phenyl Imidazole Ligands
초록 TPIF and ITPIF, are prepared in which the phenyl moiety of phenylimidazole was modified with electron-withdrawing substituents (e.g., -F). With terphenyl modification and further color tuning by adding fluorine and isopropyl groups, ITPIF showed blue phosphorescence at 456 nm as well as high quantum yields (40% in solution and 76% in PMMA film). This ITPIF complex is selected as a dopant material in the structure of blue phosphorescent organic light-emitting diodes. The highly efficient blue OLED can be realized with a maximum EQE of over 16.4% with CIE value of (0.18, 0.27). Our results demonstrate that bulky substituents are excellent candidates for the achievement of efficient phosphorescent materials and corresponding OLED devices.
저자 이상훈, 이대한, 서윤정, 윤보선, 김소연, 김진형, 강상욱, 손호진
소속 고려대
키워드 Iridium(III) complexes; OLED
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