화학공학소재연구정보센터
학회 한국화학공학회
학술대회 2008년 가을 (10/23 ~ 10/24, 부산 BEXCO)
권호 14권 2호, p.2343
발표분야 고분자
제목 Manufacture and properties of ETFE fuel cell membrane by using radiation grafting technology
초록 The electron beam radiation technology could be successfully carried out for a manufacture of ETFE [Poly(ethylene-alt-tetrafluoroethylene] membrane with a uniform and high distribution of sulfonic groups. The maximum degree of styrene-grafting existed at around 20kGy, considerably decreasing the degree of grafting above 30kGy. The hydrated ETFE film with a high degree of grafting after sulfonation could be largely swelled, showing a high treansparency in water. The methanol crossover across ETFE membrane could be much more suppressed compared to Nafion 115 membrane. On the other hand, electric power generation over ETFE membrane was slightly lower than that in Nafion 115.
저자 이동화, 조현국, 박대엽, 한도흥
소속 영남대
키워드 ETFE film; membrane; fuel cell; grafting; electron beam; styrene; DMFC; IEC; MeOH crossover
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