화학공학소재연구정보센터
학회 한국고분자학회
학술대회 2019년 가을 (10/09 ~ 10/11, 제주컨벤션센터)
권호 44권 2호
발표분야 기능성 고분자
제목 Formation of conductive overcoating layer for chemical and physical stability of PEDOT:PSS film
초록 An overcoating layer that can be applied on a flexible transparent PEDOT:PSS film was prepared by combining silica sol and organic polymer. (3-Glycidyloxypropyl)trimethoxysilane(GPTMS) was used as a precursor for the silica sol, which hydrolyzed under moisture to form silanol groups and self-condensed to form a sol under acidic conditions. Therefore, the organic polymer was poly(4-styrenesulfonic acid)(PSSA), which is acidic and water-soluble; thus, the silica precursor can form a sol and can cause chemical condensation with the silica sol under thermal conditions. However, as this protective layer was insulating, there was difficulty in conducting electricity to the lower portion through the upper contact. Therefore, a small amount of conductive layer, poly(3,4-ethylenedioxythiophene):poly(styrenesulfonate)(PEDOT:PSS), was added to the protective layer to make the overcoating layer itself conductive, thereby enabling electrical conduction to the underlying conductive film.
저자 배소영, 이진근, 김영노, 이홍주, 김중현
소속 연세대
키워드 conducting polymer; conjugated polymer; electronic conductivity; transparent electrode
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