| 학회 |
한국공업화학회 |
| 학술대회 |
2021년 가을 (11/03 ~ 11/05, 대구 엑스코(EXCO)) |
| 권호 |
25권 2호 |
| 발표분야 |
포스터-촉매 |
| 제목 |
Understanding hydrodeoxygenation reaction of vanillin to cycloalkanes over Ru/HZSM-5 catalysts in biphasic system |
| 초록 |
A complete hydrodeoxygenation(HDO) of vanillin to yield cycloalkanes was performed using bifunctional Ru loaded HZSM-5 catalysts with different metal loadings and Si/Al ratios in n-octane/water biphasic system. Both the reaction pathway and product distribution were influenced by the metal/acid balance of the catalysts. Higher metal/acid ratio promoted Caryl-C cleavage reaction, resulting in the increased yield of cyclohexane. Synergetic effect of metal and acid sites was observed in the bifunctional catalyst, attaining as high as 40-fold increase of metal efficiency in the ring hydrogenation reaction, compared to lone metal site catalyst. The effect of solvent composition was evaluated, revealing that the presence of water promoted the overall HDO reaction. By balancing metal/acid and introducing appropriate solvent system, efficient catalytic system that minimized carbon loss and improved metal efficiency for vanillin HDO was obtained. |
| 저자 |
김형주1, 양승도1, 임용현1, 하정명2, 김도희1
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| 소속 |
1서울대, 2KIST |
| 키워드 |
Hydrodeoxygenation; Bifunctional catalysts; Ru loaded zeolite; Metal-acid synergy; Metal/acid balance
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| E-Mail |
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