| 학회 |
한국고분자학회 |
| 학술대회 |
2008년 봄 (04/10 ~ 04/11, 컨벤션 뷰로(대전)) |
| 권호 |
33권 1호 |
| 발표분야 |
기능성 고분자 |
| 제목 |
Light-Driven Supramolecular Transforamtion and Controlled Release Characteristics of Self-Assemblies of Amide Dendrons |
| 초록 |
We demonstrated that the self-assembly of the amide dendrons with photoresponsive focal functionality provides an efficient route to stimuli-responsive supramolecular materials. Dendrons with photoresponsive functions respectively formed vesicular structures in aqueous phase. The vesicle of dendron with photocleavable 2-nitrobenzyl ester unit was transformed into a fibrous nanostructure upon exposure to UV irradiation in a basic aqueous solution with concurrent release of entrapped molecules. The vesicle of dendron with the focal azobenzene moiety exhibited photo-controlled behavior in the release of guest molecules from the interior or the membrane of the vesicle. These supramolecular approaches by using dendritic building blocks would provide a unique methodology to construct stimuli-responsive smart materials. |
| 저자 |
박치영, 임진오, 윤미경, 김철희
|
| 소속 |
인하대 |
| 키워드 |
self-assembly; photo-responsive
|
| E-Mail |
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