| 학회 |
한국고분자학회 |
| 학술대회 |
2010년 가을 (10/07 ~ 10/08, 대구 EXCO) |
| 권호 |
35권 2호 |
| 발표분야 |
고분자 가공/복합재료 |
| 제목 |
A Novel Application of Ionic Liquids for Facilitated Olefin Transport Membranes as a Carrier for Separation of Olefin/Paraffin Mixtures |
| 초록 |
This is the first trial for applications of ionic liquids as a carrier for olefin facilitated transport. The separation performance of ionic liquids such as MOIM+NO3- (1-methyl-3-octyl imidazolium nitrate) and BMIM+BF4- (1-butyl-3-methyl imidazolium tetrafluoroborate) was investigated for olefin/paraffin mixtures. The formation of free cations, which was confirmed from slight shift of N-O stretching band upon propylene exposure by FT-IR spectra, may induce interactions between the free cations and olefin molecules such as propylene and ethylene, as supported by quantum mechanical ab initio calculations, resulting in separation performances of olefin/paraffin mixture. The improved separation performance will be interpreted by apparent diffusion and solubility coefficients, measured by transient sorption methods. |
| 저자 |
이정현1, 원종옥2, 최용석1, 전성현1, 강용수1
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| 소속 |
1한양대, 2세종대 |
| 키워드 |
ionic liquid; facilitated transport; membrane; olefin separation
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| E-Mail |
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