학회 | 한국공업화학회 |
학술대회 | 2015년 가을 (11/04 ~ 11/06, 제주국제컨벤션센터(ICCJEJU)) |
권호 | 19권 2호 |
발표분야 | 디스플레이_포스터 |
제목 | Synthesis and properties of photoinduced refractive index chnage polymers |
초록 | Refractive index changing materials by photo-irradiation or electrical field were widely utilized to optical, electrical and biological applications. The trans-cis photoisomerization of azobenzene is well-defined and extensively applied process. Irradiation with light produces the cis isomer, which has a bent conformation and much larger dipole moment. As a result of photoisomerization of azobenzene, the polymer bearing azobenzene as a side-chain have a large refractive index change. In this study, we have investigated azobenzene containing photo induced refractive index change polymers. The methacrylate monomers and azobenzene side chain polymers with various ratio were synthesized via radical polymerization. The molecular structure and properties of polymers were characterized by NMR, UV-vis, DSC and GPC. The refractive index change properties of prepared polymers after UV-irradiation were also studied. |
저자 | 가재원1, 조진한2, 이미혜1, 김진수1, 최미진1, 전인혜1 |
소속 | 1한국화학(연), 2고려대 |
키워드 | azobenzene; refractive index change |