화학공학소재연구정보센터
학회 한국고분자학회
학술대회 2009년 가을 (10/08 ~ 10/09, 광주과학기술원 오룡관)
권호 34권 2호
발표분야 OLED 소재 및 소자기술 동향(분자전자 부문위원회)
제목 Silsesquioxane dielectrics for organic thin film transistors and spin-coated CdS semiconductor thin films
초록 Silsesquioxane thin films are strong candidates as dielectric thin films for various electronic applications. Their dielectric constant values are thought to be partially due to Si-OH groups inside the films which is understood in terms of electronic, ionic, and orientational polarizations using Debye equation. Distinct clockwise capacitance-voltage (C-V) hysteresis in aminopropyl-silsesquioxane thin films is originated from amphoteric charge trap behavior due to the coexistence of N(Si≡)2 and E’ centers. 1,2-bis(trimethoxysilyl)ethane and methyltrimethoxysilane monomers were used for synthesis of ethylene-bridged copolymer owing to condensation polymerization. we have investigated a new solution-processed approach to the synthesis of semiconducting CdS films for use in TFT devices, exhibiting n-channel TFT characteristics with an excellent field-effect mobility (a saturation mobility of ~ 48 cm2V-1s-1) and low voltage operation (< 5 V).
저자 정현담
소속 전남대
키워드 Silsesquioxane; dielectrics; OTFT; Debye equation; C-V hysteresis; CdS
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