| 학회 |
한국화학공학회 |
| 학술대회 |
2019년 가을 (10/23 ~ 10/25, 대전컨벤션센터) |
| 권호 |
25권 2호, p.1542 |
| 발표분야 |
에너지 환경 (Energy and Environment) |
| 제목 |
Electrochemical Investigation on LiCl-KCl-CdCl2-NdCl3 for Developing Nd Recycling Process |
| 초록 |
Electrochemical behavior of NdCl3 and CdCl2 with inert cathode and liquid cadmium cathode in LiCl-KCl eutectic at 500 ℃ was studied. Metallic Nd can be oxidized by CdCl2 and concentration monitoring technique of NdCl3 which was oxidized from Nd metal by cyclic voltammetry of CdCl2 was established. Whereas recovered Nd by conventional pyrometallurgical method was obtained as a form of metal powder and has low recovery efficiency, because of its disproportionation reaction, liquid cadmium cathode can suppress disproportionation reaction which results in increase of Nd recovery efficiency. Comparison of cyclic voltammetry of NdCl3 with cadmium film electrode and liquid cadmium cathode shows deoxidized Nd on liquid cadmium cathode forms Cd11Nd intermetallics. |
| 저자 |
전영환, 정관윤, 허정호, 신혜원, 박재영
|
| 소속 |
울산과학기술원 |
| 키워드 |
에너지 환경 |
| E-Mail |
|
| VOD |
VOD 보기 |
| 원문파일 |
초록 보기 |
