화학공학소재연구정보센터
학회 한국고분자학회
학술대회 2021년 가을 (10/20 ~ 10/22, 경주컨벤션센터)
권호 46권 2호
발표분야 분자전자 부문위원회 Ⅰ,Ⅱ
제목 Highly Selective, Sensitive and Reusable Colormetric Chemosensor for Naked-eye Detection of Hydrogen Sulfide under Versatile Conditions
초록 In this presentation, we report a new colorimetic chemosensor based on Benzodipyrrolidone moiety for the detection of hydrogen sulfide (H2S). which can affect injurious defect to human body. Highly sensitive (limit of detection : 1.56uM) and selective reactivity of BDP-Br enables colorimetric response of the BDP-Br solution to the H2S by showing well-defined visible color change from yellow to colorless. We also have investigated BDP-Br does not show any differences with analytes including thiol group in UV-vis absorption so that it can be worked as high selective H2S chemosensor. Based on systemic characterizations, including UV-vis absorption and NMR spectral analyses, we revealed that BDP-Br return to precursor when it reacts with H2S. This advantageous property suggests that BDP-Br can be practically applicated for reusable chemosensor under versatile conditions.
저자 조나영, 오병민, 전혜원, 이은혜, 김종현
소속 아주대
키워드 Colorimetric chemosensor; Hydrogen sulfide detection; Benzodipyrrolidone; sensing mechanism
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