화학공학소재연구정보센터
학회 한국화학공학회
학술대회 2006년 가을 (10/27 ~ 10/28, 고려대학교)
권호 12권 2호, p.1590
발표분야 분리기술
제목 Breakthrough Analysis of Adsorption of Toluene Vapor in a Fixed-Bed of Granular Activated Carbon
초록 Toluene vapor was adsorbed in a laboratory-scale packed-bed adsorber using granular activated carbon(GAC) at constant pressure(101.3 kPa). The adsorber was operated batchwise with the charge of GAC in the range of 2-4 g to obtain the breakthrough curves of toluene vapor. Experiments were carried out at different temperatures(25-50oC), sparger temperatures(20-30oC), and flow rates of nitrogen(80-150 cc/min) to investigate the effects of these experimental variables on the breakthrough curves. The deactivation model was tested for these curves by using the analogy between the adsorption of toluene vapor and the deactivation of adsorbent particles. The observed values of the adsorption rate constant and the deactivation rate constant were evaluated through analysis of the experimental breakthrough data using a nonlinear least squares technique. A good agreement of the deactivation model was obtained with the experimental breakthrough data more accurately compared to the adsorption isotherms in the literature.
저자 최병식1, 김달형1, 천미선1, 이상원1, 박상욱1, 이재욱2
소속 1부산대, 2서강대
키워드 toluene vapor; activated carbon; breakthrough curve; deactivation model
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