| 학회 |
한국고분자학회 |
| 학술대회 |
2021년 가을 (10/20 ~ 10/22, 경주컨벤션센터) |
| 권호 |
46권 2호 |
| 발표분야 |
기능성 고분자 |
| 제목 |
Topological effects of poly(glycidol)s for self-healing material based on the boronic ester |
| 초록 |
Self-healing polymers are able to shuffle dynamic covalent B-O bonds through transesterification and re-esterification under ambient humidity conditions. In this work, dynamic covalent bond (B-O) was introduced by addition of 4-Vinylphenylboronic acid into topology controlled poly(glycidol)s (PGDs) (i.e. cyclic branch PGD, hyperbranched PGD, and perfect linear PGD) and polymer networks were formed by simple radical curing process without initiator, which were confirmed by DSC, GPC, and NMR analysis. On the basis of the unique topologies of the PGDs, significant correlations between the topology and self-healing effects were investigated by nano-indentation and scratch tester. |
| 저자 |
최순영1, 이상호1, 이동욱2, 박영일1, 김진철1, 정지은1
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| 소속 |
1한국화학(연), 2울산과학기술원 |
| 키워드 |
self-healing; poly(glycidol)s; radical reaction; boronic ester
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| E-Mail |
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