화학공학소재연구정보센터
학회 한국공업화학회
학술대회 2020년 가을 (10/28 ~ 10/30, 광주 김대중컨벤션센터(Kimdaejung Convention Center))
권호 24권 1호
발표분야 포스터-전기화학
제목 Nafion composite membrane contained functionalized MOF for vanadium redox flow battery
초록 Vanadium redox flow battery (VRFB) has been studied because of long life and stability. The membrane constituting the VRFB blocks the anolyte and catholyte. Nafion, the most widely used commercial ion exchange membrane, has excellent chemical stability and conductivity. However,  since Nafion has an ion cluster of a size capable of permeating vanadium multivalent, one vanadium ions permeate to the other. It reduces the capacity of the VRFB. Functionalized Metal-Organic Framework(MOF) was selected as the material of the composite membrane. MOF is a crystalline compound and is a porous material. Al-based CAU-10-H has a micropore and a channel type window of similar size to vanadium multivalent. In this study, two hydrophilic functional groups, -SO3H and -OH, were applied to CAU-10-H. The composite membrane was fabricated by dispersing functionalized MOFs to Nafion. The physicochemical properties of the composite membrane were compared with Nafion115.
저자 최현진1, 윤철상1, 임성남1, 배종욱2, 박제성1
소속 1한국생산기술(연), 2성균관대
키워드 Vanadium redox flow battery; Metal-Organic framework; composite membrane; ESS
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