화학공학소재연구정보센터
학회 한국공업화학회
학술대회 2018년 봄 (05/02 ~ 05/04, 대구 엑스코(EXCO))
권호 22권 1호
발표분야 환경에너지_포스터
제목 Carbonyl sulfide removal using scheelite type alkaline-earth metal tungstate adsorbents
초록 Recently, there has been much interest in research into more efficient and environmentally friendly development methods. Among them, coal gasification fuel cell power generation (IGFC) is attracting worldwide attention. IGFC, the next generation power generation technology, is known to be more effective at reducing greenhouse gas emissions than coal gasification combined cycle (IGCC). However, a small amount of sulfur compounds is produced by the gasification of coal, which can be caused to poison the catalyst of the fuel cell, so it must be controlled to a few ppm or less. Therefore, in this study, we tried to find a catalyst to remove COS, one of the sulfur compounds that cause catalyst poisoning. Based on WO3, basic alkaline earth metals were added to improve the acid gas adsorption capacity. We synthesized scheelite type catalysts of MWO4. The characteristics of the synthesized catalysts were analyzed by XRD, BET, SEM, and COS removal test was performed at 400 ℃.
저자 김준영1, 박노국1, 이승종2, 홍진표3, 강미숙1
소속 1영남대, 2고등기술(연), 3한국전력공사 전력(연)
키워드 Carbonyl sulfide; Adsorbent; Scheelite type; MWO4; Surface basicity; Optimal alignment
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