| 학회 |
한국공업화학회 |
| 학술대회 |
2015년 봄 (04/29 ~ 05/01, BEXCO (부산)) |
| 권호 |
19권 1호 |
| 발표분야 |
촉매_포스터 |
| 제목 |
Glycerol functionalized imidazolium tricationic room temperature ionic liquids synthesis and application for 2-azidoalcohol synthesis from epoxide |
| 초록 |
The new tricationic room temperature ionic liquids (RTILs) based on 3-methylimidazolium were synthesized form glycerol. The RTILs presented interesting physicochemical properties at different temperature. The Lewis acidity of prepared ionic liquid was determined by IR spectroscopy. The [GLY(mim)3][OMs] IL showed highest Lewis acidic behavior. The catalytic activity and reusability of these tricationic RTILs were investigated for 2-azidoalcohol synthesis from epoxide and sodium azide. The prepared tricationic RTILs in presence of water as proton source exhibited high catalytic activity compared to monotricationc ILs. |
| 저자 |
Avinash Chaugule, Ashif Tamboli, 김헌
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| 소속 |
명지대 |
| 키워드 |
: Ionic liquid; glycerol; 3-methylimidazolium; 2-azidoalocohol
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| E-Mail |
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