| 학회 |
한국공업화학회 |
| 학술대회 |
2019년 가을 (10/30 ~ 11/01, 제주국제컨벤션센터(ICC JEJU)) |
| 권호 |
23권 2호 |
| 발표분야 |
포스터_환경·에너지 |
| 제목 |
Highly Efficient Photocatalytic Carbon Dioxide Reduction with Cationic Heteroleptic Iridium(III) Photosensitizers Containing Arylsilyl Substituents |
| 초록 |
Herein, we report on the synthesis, photophysical/electrochemical properties, and excited-state properties of a series of heteroleptic Ir(III) complexes ([Ir(C^N)2(N^NAryl)]+, IrP-Ph) possessing aryl-extended bipyridyl moiety (C^N = (2-pyridyl)benzo[b]thiophen-3-yl (btp); N^NAryl = 4,4′-Y2-bpy (Y = –PhSi(Ph)3) with those of non-extended case for comparison. Their photosensitizing abilities were tested in a homogeneous condition (IrP + ReP) and a mixed heterogeneous photocatalytic system consisting of Ir(III) photosensitizer and Re(I) catalyst (ReP)-immobilized TiO2 catalytic particles (IrP + TiO2/Re(I)), where ReP is fac-[Re(4,4′-Y2-bpy)(CO)3Cl] (Y = CH2PO(OH)2), and the electron donor (ED) is 1,3-dimethyl-2-phenyl-1,3-dihydrobenzimidazole (BIH). Scheme 1 describes the chemical structures of new phenyl-substituted Ir(III) photosensitizer (IrP-Ph) and key components for photolysis with its overall photolysis processes. |
| 저자 |
최민수, 조주형, 이대한, 나수원, 김철훈, 강상욱, 손호진
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| 소속 |
고려대 |
| 키워드 |
Photocatalytic Carbon Dioxide Reduction; photosensitizer; Ir complexes
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| E-Mail |
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