화학공학소재연구정보센터
학회 한국고분자학회
학술대회 2007년 봄 (04/12 ~ 04/13, 제주 ICC)
권호 32권 1호
발표분야 고분자 합성
제목 Synthesis and characterization of iron catalysts for ethylene polymerization based on 4,5-bis(imino) 2,3,7,8-tetrahydro-1H,6H-acridyl ligands.
초록 Here we report the synthesis and characterization of a series of iron catalysts based on 4,5-bis(imino) 2,3,7,8-tetrahydro-1H,6H-acridyl ligands. The chelating ligands were synthesized by condensation between 2,3,7,8-tetrahydro-1H,6H-acridine-4,5-dione and anilines with variable 2,6 – substituents. All catalysts showed good activity towards polymerization The polymerization reactions were characterized by an induction period of few minutes depending on the structure of catalyst.
저자 비누, 김일, 박대원, 하창식
소속 부산대
키워드 Ethylene polymerization; late transition metal catalyst; polymer microstructure
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