| 학회 |
한국고분자학회 |
| 학술대회 |
2007년 가을 (10/11 ~ 10/12, 일산킨텍스) |
| 권호 |
32권 2호 |
| 발표분야 |
고분자 합성 |
| 제목 |
Copolymerization of Ethylene oxide and Epibromohydrin using Cationic Ring-Opening Polymerization |
| 초록 |
The well-defined copolymer derived from ethylene oxide(EO) and epibromohydrin(EBH) was synthesized by the cationic ring-opening polymerization with 1,4-butanediol as an initiator and BF3O(C2H5)2 as a catalyst system. This polymerization was proceeded by activated monomer (AM) mechanism to control the molecular weight, narrow molecular weight distribution, and the functionality. Also this polymerization had the living polymerization characteristic. The structure and the composition of synthesized copolymers have been characterized by 1H-NMR spectroscopy. The molecular weight and the molecular weight distribution of their copolymer have been analyzed by gel-permeation chromatography (GPC) |
| 저자 |
정권영1, 이범재1, 이정환1, 유호준1, 김나리2, 김두환1, 이종섭1, 신범식1, 김태중1
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| 소속 |
1충남대, 2춤남대 |
| 키워드 |
Poly(EO-co-EBH); Cationic ring-opening polymerization; AM mechanism
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| E-Mail |
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