| 학회 |
한국공업화학회 |
| 학술대회 |
2008년 봄 (05/09 ~ 05/10, 한양대학교(안산)) |
| 권호 |
12권 1호 |
| 발표분야 |
고분자 |
| 제목 |
Synthesis of the polyurethane using the polyether which has the azide groups |
| 초록 |
The well-defined copolymers derived from epichlorohydrin(ECH) and tetrahydrofuran(THF) were synthesized by the cationic ring-opening polymerization with 1,4-butandiol as initiator and BF3∙THF complex as catalyst system. This polymerization was proceeded by activated monomer (AM) mechanism to control molecular weight, narrow molecular weight distribution and high difunctionality. Poly(GA-co-THF) was synthesized using polymerization of ECH and THF followed by azidation with NaN3. The polyurethane was synthesized from poly(GA-co-THF) as prepolymer, N-100/IPDI mixture as curing agent and TPB(Triphenylbismuth)/MA(Maleic anhydride) mixture as curing catalyst. |
| 저자 |
김태중, 이범재, 김두환, 신범식, 이종섭, 정권영
|
| 소속 |
충남대 |
| 키워드 |
poly(GA-co-THF); cationic ring-opening polymerization; AM mechanism; azidation; polyurethane
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| E-Mail |
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