화학공학소재연구정보센터
학회 한국고분자학회
학술대회 2009년 가을 (10/08 ~ 10/09, 광주과학기술원 오룡관)
권호 34권 2호
발표분야 고분자 나노 구조물의 합성, 분석 및 응용(국제심포지움)
제목 AFM ASSISTED SYNTHESIS AND STUDY OF COMPLEX POLYMER NANOSTRUCTURES
초록 We will present a strategy based on AFM that allows investigating macromolecules as isolated objects. It is applied to the analysis of the multistep synthesis of polymers, presently poly(chloroethyl vinyl ether)-based systems, with complex chain architecture, such as stars, macrocycles, or more sophisticated molecular objects. Magnification of the obtained macromolecules by grafting onto processes allows their AFM imaging as isolated molecular objects as well as performing statistical analysis over a large set of molecules. Through this approach the efficiency of the applied synthesis can be readily evaluated but also the different side processes operating during the synthesis and yielding secondary polymer structures can be identified and their mechanisms of formation determined. This will be highlighted by the presentation of several examples
저자 Alain Deffieux1, Michel Schappacher2
소속 1CNRS / Univ. Bordeaux, 2Univ. Bordeaux
키워드 controlled polymerization; comb polymer; chain architecture; AFM imaging; molecular analysis
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