화학공학소재연구정보센터
학회 한국화학공학회
학술대회 2016년 가을 (10/19 ~ 10/21, 대전컨벤션센터)
권호 22권 2호, p.1891
발표분야 에너지
제목 Free base Porphyrin Polymers and their Metal Complexes for Supercapacitor and Methanol Electro-Oxidation
초록 Investigation towards the development of supercapacitor materials have mainly focused on the metal oxides, graphenes, and their composites. Thus, there is a need to explore other potential materials to expand the technology. A recent emerging material, CMPs (Conjugated Microporous Polymers), was investigated to study its applicability for supercapacitor and methanol oxidation. The polymeric porphyrin based material, synthesized via suzuki-cross coupling, offers high surface area to provide more active sites, extended π-conjugation for conductivity and formation of transition metal complexes. The formation of the porphyrin macrocycle was determined by XPS analysis showing two distinct peaks at 399.8 eV and 397.8 eV. This work was supported by Basic Science Research Program through the National Research Foundation of Korea (NRF) funded by the Ministry of Science, ICT and Future Planning (NRF-2016R1C1B2008694).
저자 Alan Christian Lim, Harsharaj Sayaji Jadhav, Gaurav Thorat, 서정길
소속 명지대
키워드 고효율; 에너지 소재
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