화학공학소재연구정보센터
학회 한국고분자학회
학술대회 2005년 가을 (10/13 ~ 10/14, 제주 ICC)
권호 30권 2호
발표분야 고분자 합성
제목 Synthesis of gold nanoparticle stabilized by ω-thiolated poly(ethylene oxide)
초록 Transition metal nano clusters may be used for a variety of application fields. Specifically, nanosized Au particles have been used in the bio-senser or the drug delivery system. In this respect, we developed new process to prepare nanosized Au particle using ω-thiolated poly(ethylene oxide)(PEO) as a polymeric stabilizer. n-Butyllithium-initiated ring-opening polymerization of ethylene oxide in the presence of t-BuO-K+ was successfully carried out in the mixture of benzene and dimethylsulfoxide at 40℃ for 48h, followed by ω-thiolation by reacting with propylene sulfide. The functionalization yields were over 97 mol%. In this presentation, we will report the result for gold nanoparticle using ω-thiolated PEO
저자 이철한1, 김지희2, 박형수3, 곽순종1, 황승상1, 김광웅1, 김정안4, 박흥목3
소속 1한국과학기술(연), 2율촌화학 / 한국과학기술(연), 3서강대, 4경희대
키워드 nanoparticle; Au; PEO
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