| 초록 |
C1 chemistry, which is based on conversion of C1-hydrocarbons, such as methane and carbon dioxide, is a predominant area to produce diverse useful-materials. Among the related technology, electro-chemical conversion of those hydrocarbons is considered as an important method. Despite high attention in electro-chemical conversion to syngas or alcohols, only a few studies were reported. For this reason, mechanism of the electro-chemical conversion of methane is still being studied to secure fundamental understandings of those reactions. This study aims to suggest mechanisms of electro-chemical conversion of methane to alcohols, mainly to methanol or ethanol, via electro-catalytic reaction on Fe2O3 or Nb-doped NiO with ZrO2. The results will be compared with experiments. |
