| 학회 | 한국공업화학회 |
| 학술대회 | 2017년 봄 (05/10 ~ 05/12, 광주 김대중컨벤센센터(Kimdaejung Convention Center)) |
| 권호 | 21권 1호 |
| 발표분야 | 촉매 |
| 제목 | Development of novel metal catalyst for reductive amination of alcohol |
| 초록 | The reductive amination reaction consists of three steps of reactions; dehydrogenation, dehydration, and hydrogenation. Therefore, the development of multi-functional catalyst to achieve the one-pot three-step reaction is very important to develop an efficient process to synthesize primary amine directly from alcohol. In this study, the reactivity of heterogeneous metal catalysts containing Ni, Cu, Zr, Sn, Co, Cr, and Zn synthesized by precipitation method was compared through model amination reaction. To improve the efficiency of reductive amination reaction, cobalt (Co) or chromium (Cr) was proposed to be used as the component of metal catalyst since they were acknowledged as having good activity in amination reaction. The amination of ethylene glycol with aniline was applied as the model reaction. Through this catalyst screening procedure, the effect of metal composition on the reactivity for the amination was confirmed. |
| 저자 | 김보라, Nguyen Tan Phat, 이홍식, 조진구 |
| 소속 | 한국생산기술(연) |
| 키워드 | Heterogeneous; Metal catalyst; Reductive amination |
